Fire, or combustion is when fuel reacts with oxygen to release heat energy. Combustion can be slow or fast depending on the amount of oxygen available. Combustion that results in a flame is very fast and is called burning. Combustion can only occur between gases.
The fuel must be heated to its ignition temperature for combustion to occur. The reaction will keep going as long as there is enough heat, fuel and oxygen. This is known as the fire triangle.
Fire Triangle
The fire triangle, or combustion triangle, is the three components needed to ignite and sustain a fire. The three ingredients of a fire triangle are heat, fuel and oxygen.
If just one of these components is removed, the fire triangle will collapse, and the fire will be extinguished.
Let’s explore these components in more detail:
1. Heat
A source of heat is required in order for ignition to occur, and different materials have different ‘flash points’ e.g. the lowest temperature at which they ignite.
Unfortunately, combustion reactions also produce heat as they burn, further increasing the temperature of the fuel. For some types of fire, the heat can be cooled with the application of water.
2. Fuel
A fire cannot begin if there is no material to burn. Homes and businesses are full of flammable materials, such as paper, oil, wood and fabrics. Any of these can serve as a fuel for a fire.
Some materials burn more easily than others. Fuels are probably the most difficult ‘side’ of the fire triangle to remove, so it’s wise to store them appropriately to prevent them from becoming a fire hazard.
3. Oxygen
To sustain the combustion reaction, oxygen (or an oxidizing agent) is needed, as it reacts with the burning fuel to release heat and CO2. Earth’s atmosphere consists of 21% oxygen, so there is plenty available to trigger a fire if the other two components are present.
Fire blankets and certain fire extinguishers remove the oxygen ‘side’ of the triangle by removing it or displacing it, causing suffocation and thereby ceasing the combustion reaction.
Fire Facts
Fire normally generates three different types of hazards: heat, oxygen depletion and smoke.
Heat: The most obvious hazard is heat. Although the majority of fire deaths are caused by smoke, many deaths and severe injuries are caused by burns. When the temperature of skin reaches 133°F, it’s associated with pain.
A room fire can range from 212°F at floor level to 2192°F at the ceiling. As temperatures rise above 260°F, skin will burn with permanent injuries, and if extremely hot air is inhaled it can scorch internal organs.
Oxygen Depletion: A decrease in the partial pressure of oxygen (PO2) can cause serious harm to the brain. As fire roars and grows, it consumes enormous amounts of Oxygen. I.e., a 5x5x10 fire in a 2000sqf house will normally consume all the oxygen inside the home in under 30 seconds. The brain needs a constant supply of oxygen. If the oxygen intake is interrupted for more than 3 minutes the brain can suffer irreversible damage.
Smoke: Smoke is all the airborne products of the pyrolysis and combustion of materials, and it can be very toxic. It’s particles, gases such as carbon monoxide, volatilized organic molecules, aerosols, and free radicals are deadly when inhaled. A fire often gives off a dark, thick smoke. In a serious fire, it can be hard to see what’s ahead and where you’re going. Breathing in even the smallest amount of the toxic smoke can disorient a person quickly, causing them to pass out.
How to prevent and stop the spread of fires
Heat: Heat usually originates from people smoking, poorly maintained machinery and equipment, hot work, neglected electrical, or arson.
Heat is occasionally inevitable to some operations in which case it is important that fuel is kept away from heat or that it’s being carefully managed under a controlled environment.
Fuel: As previously mentioned, flammable materials (fuel) are materials that burn readily in a normal atmosphere. It’s important that all these flammable materials are identified and that appropriate measures are taken to control them. You need to store these materials appropriately, and in appropriate quantities, furthermore you need to maintain good housekeeping. For extra volatile flammable materials, make sure that these are stored with extra precautions.
Oxygen: The air we breathe contains ~21% of oxygen. With just a small increase to say 23% oxygen – a fire will burn hotter and more fiercely. With just a little more oxygen in the air, a fire can become almost impossible to put out. The oxygen bottles should always be kept close to an exit door where firefighters can easily remove them from the building, and away from combustible materials.